Pleated aligned web filter

ABSTRACT

A filter element that has rows of folded pleats and includes a nonwoven filtration web that contains thermoplastic fibers, a majority of which fibers are aligned at 90°±20° with respect to the row direction. The filter elements can be made by forming rows of pleats in such a nonwoven web and cutting the web to a desired size and shape. The filter elements can provide improved mechanical and filtration properties.

This invention pertains to pleated filters that have fiber alignment in the direction of web formation.

BACKGROUND

Meltblown nonwoven fibrous webs are used for a variety of purposes including filtration (e.g., flat web and pleated filters), insulation, padding and textile substitutes. References relating to meltblown nonwoven fibrous webs include U.S. Pat. No. 3,959,421 (Weber et al.), U.S. Pat. No. 4,622,259 (McAmish et al.), U.S. Pat. No. 5,075,068 (Milligan et al.), U.S. Pat. No. 5,141,699 (Meyer et al.), U.S. Pat. No. 5,405,559 (Shambaugh), U.S. Pat. No. 5,652,048 (Haynes et al.), U.S. Pat. No. 5,665,278 (Allen et al.), U.S. Pat. No. 5,667,749 (Lau et al.), U.S. Pat. No. 5,772,948 (Chenoweth) and U.S. Pat. No. 5,811,178 (Adam et al.). References relating to pleated filters include U.S. Pat. No. 4,547,950 (Thompson), U.S. Pat. No. 5,240,479 (Bachinski), U.S. Pat. No. 5,709,735 (Midkiffet al.), U.S. Pat. No. 5,820,645 (Murphy, Jr.), U.S. Pat. No. 6,521,011 B1 (Sundet et al. '011) and U.S. Pat. No. D449,100 S (Sundet et al. '100), and U.S. Patent Application Publication Nos. U.S. 2003/0089090 A1 (Sundet et al. '090) and U.S. 2003/0089091 A1 (Sundet et al. '091).

SUMMARY OF THE INVENTION

Nonwoven web manufacture typically involves deposition of fibers on a moving collector surface. Perhaps partly as a consequence of this motion, the collected web may exhibit a small degree of fiber alignment in the machine direction, and to a small extent some anisotropic physical properties (e.g., tensile strength) in the machine and transverse directions. Nonwoven web manufacturers often strive however to make products having well-balanced and generally isotropic physical properties.

We have found that by forming nonwoven webs having much greater than normal fiber alignment in the machine direction and forming the resulting webs into pleated filtration media having pleats generally transverse to the machine direction, we can obtain filters with improved mechanical properties or improved filtration performance. The present invention provides, in one aspect, a filter element having rows of folded pleats comprising a nonwoven filtration web of thermoplastic fibers a majority of which are aligned at 90°±20° with respect to the row direction.

The invention provides, in another aspect, a method for forming a pleated filter element, comprising forming rows of pleats in a nonwoven filtration web comprising thermoplastic fibers a majority of which are aligned at 90°±20° with respect to the row direction and cutting the pleated filter element to a desired size and shape.

These and other aspects of the invention will be apparent from the detailed description below. In no event, however, should the above summaries be construed as limitations on the claimed subject matter, which subject matter is defined solely by the attached claims, as may be amended during prosecution.

BRIEF DESCRIPTION OF THE DRAWING

FIG. 1 is a schematic side view of a meltblowing apparatus for making nonwoven webs having fibers substantially aligned in the machine direction.

FIG. 2 is an overhead view of a vacuum collector for use in the apparatus of FIG. 1.

FIGS. 3-6 are radar plots showing fiber alignment.

FIG. 7 is a perspective view of pleated filtration media.

FIG. 8 is a perspective view, partially in section, of a pleated filter mounted in a frame.

FIG. 9 is a graph showing filter pressure drop vs. air velocity.

FIG. 10 is a schematic illustration of an apparatus for making the disclosed pleated filters.

Like reference symbols in the various figures of the drawing indicate like elements. The elements in the drawing are not to scale.

DETAILED DESCRIPTION

The phrase “nonwoven web” refers to a fibrous web characterized by entanglement or point bonding of the fibers.

The phrase “filtration web” refers to a porous web capable of removing at least particles having an average particle diameter greater than 10 μm from a stream of air flowing at a 0.5 m/sec face velocity at an initial pressure drop no greater than about 50 mm H₂O.

The phrase “attenuating the filaments into fibers” refers to the conversion of a segment of a filament into a segment of greater length and smaller diameter.

The word “meltblowing” refers to a method for forming a nonwoven web by extruding a fiber-forming material through a plurality of orifices to form filaments while contacting the filaments with air or other attenuating fluid to attenuate the filaments into fibers and thereafter collecting a layer of the attenuated fibers.

The phrase “meltblown web” refers to a nonwoven web made using meltblowing.

The phrase “nonwoven die” refers to a die for use in meltblowing.

The phrases “meltblown fibers” and “blown microfibers” refer to fibers made using meltblowing.

The phrase “machine direction” when used with respect to a meltblown web or to a meltblowing apparatus for meltblown web formation refers to the in-plane direction of web fabrication.

The phrase “transverse direction” when used with respect to a meltblowing apparatus or a meltblown web refers to the in-plane direction perpendicular to the machine direction.

The phrase “row direction” when used with respect to a pleated filter element refers to a direction generally parallel to the pleat ridges and valleys in a filter element having a folded structure with parallel, generally sharp-edged creases, and to a direction generally parallel to the pleat crowns and base regions in a filter element having a corrugated structure with parallel, generally smooth undulations.

The term “self-supporting” when used with respect to a web refers to a web having sufficient coherency and strength so as to be drapable and handleable without substantial tearing or rupture, and when used with respect to a pleated filter refers to a filter whose pleats have sufficient stiffness so that they do not collapse or bow excessively when subjected to the air pressure typically encountered in forced air ventilation systems.

A variety of polymers may be employed to make the disclosed aligned fiber webs. Representative polymers are thermoplastic, extrudable and can be processed using a meltblowing apparatus, and include polyolefins such as polyethylene, polypropylene or polybutylene; polyamides; polyesters such as polyethylene terephthalate; and other materials that will be familiar to those skilled in the art. Polyolefins are particularly preferred.

A variety of sorbent particles can be added to the nonwoven webs if desired. Representative sorbent particles are disclosed in U.S. Pat. No. 3,971,373 to Braun, U.S. Pat. No. 4,429,001 to Kolpin et al. and U.S. Pat. No. 6,102,039 to Springett et al. Activated carbon and alumina are particularly preferred sorbent particles. Mixtures of sorbent particles can be employed, e.g., to absorb mixtures of gases, although in practice to deal with mixtures of gases it may be better to fabricate a multilayer pleated filter employing separate sorbent particles in the individual layers.

A variety of primary and secondary fluid streams may be employed to make the disclosed filtration webs. Air is an especially convenient fluid for both purposes. The remainder of this application will discuss the use of air, sometimes referred to as “primary air” or as “secondary quench air” as the context may require. Those skilled in the art can readily employ other fluids (e.g., carbon dioxide, nitrogen or water) with appropriate modification of the operating parameters described below.

FIG. 1 shows a schematic side view of meltblowing apparatus 10. Molten polymer enters meltblowing die 12 through inlet 14 and passes through die cavity 16. Small orifices (not shown in FIG. 1) in die tip 18 cause the molten polymer to form filaments 22 upon exiting die 12. Primary air supplied through inlets 20 impinges upon the filaments 22 and attenuates them into fibers 24. Fibers 24 land on flat collector 26 and form nonwoven web 28 which can be drawn away from collector 26 in the direction of web formation (viz., the machine direction) 30 by a suitable take-up apparatus (not shown in FIG. 1). On route to collector 26, secondary quench air supplied to ducts 32 arrayed across the width of web 28 impinges upon the filaments or fibers, causing the fibers to oscillate to and fro generally in and against the machine direction. The collected fibers in the resulting web 28 are substantially more aligned in the machine direction than would be the case without the secondary quench air supply. The web's machine direction and transverse direction mechanical properties (e.g., its machine direction and transverse direction stiffness and tensile strength) also exhibit greater anisotropy than when a secondary quench air supply is not employed.

Viewed from the side (or transverse direction) using high-speed photography, fibers 24 are laid down on collector 26 in a “paintbrush” fashion. Measured at the collector, the oscillations can have a very large machine direction amplitude, e.g., more than one fourth the die to collector distance (“DCD”) and in some instances more than half the DCD. Several operating conditions may be especially desirable to achieve such paintbrush deposition. For example, the oscillations may occur regularly, may have increasing amplitude en route to the collector, and may have a wavelength for one complete cycle that is less than the distance from the secondary quench air outlets to the collector. Preferably the distance from the secondary quench air outlets to the collector is not overly long. The fibers may in some instances exhibit a whip-like action at their peak machine direction displacement en route to the collector, and may momentarily move towards the meltblowing die rather than always moving toward the collector. Apparent fiber breakage can sometimes be seen as such whip-like action occurs.

We have been able to tease fibers with discrete lengths (e.g., between about 1 and about 10 cm, along with occasional shorter or longer fibers) from the collected webs using tweezers. Ordinarily it is quite difficult to remove any fibers (or any fibers of such lengths) from conventional nonwoven webs, as the fibers typically are restrained in the web by fiber-to-fiber bonding or by interfiber entanglement.

Web 28 can be pleated as is, or further treated. Preferably a heat treatment (e.g., annealing) is employed to stiffen the web. Heat treatments may however make it more difficult to tease fibers from the web, as the fibers may tend to fracture and the web may have greater inter-fiber bonding or entanglement. Preferred annealing times and temperatures will depend on various factors including the polymeric fibers employed. As a general guide, annealing times and temperatures of about 100° C. up to the polymer melting point for a time less than about 10 minutes are preferred.

A vacuum can optionally be drawn thorough orifice 34 to assist in consolidating web 28. Overdensification (e.g., using calendaring) may however destroy the web's filtration capability. Electric charge can be imparted to the fibers by contacting them with water as disclosed in U.S. Pat. No. 5,496,507 to Angadjivand et al., corona-treating as disclosed in U.S. Pat. No. 4,588,537 to Klasse et al., hydrocharging as disclosed, for example, in U.S. Pat. No. 5,908,598 to Rousseau et al. or tribocharging as disclosed in U.S. Pat. No. 4,798,850 to Brown. Additives may also be included in the fibers to enhance the web's filtration performance, mechanical properties, aging properties, surface properties or other characteristics of interest. Representative additives include fillers, nucleating agents (e.g., MILLAD™ 3988 dibenzylidene sorbitol, commercially available from Milliken Chemical), UV stabilizers (e.g., CHIMASSORB™ 944 hindered amine light stabilizer, commercially available from Ciba Specialty Chemicals), cure initiators, stiffening agents (e.g., poly(4-methyl-1-pentene)), surface active agents and surface treatments (e.g., fluorine atom treatments to improve filtration performance in an oily mist environment as described in U.S. Pat. Nos. 6,398,847 B1, 6,397,458 B1, and 6,409,806 B1 to Jones et al.). The types and amounts of such additives will be apparent to those skilled in the art.

The completed webs may have a variety of effective fiber diameter (“EFD”) sizes, basis weights and solidity (ratio of polymer volume to web volume) values. Preferred EFDs are about 8 to about 25, more preferably about 10 to about 25 μm. Preferred basis weights are about 50 to about 100 g/m². Preferred solidity values are about 5 to about 15%.

The disclosed webs have substantial machine direction (direction of motion or direction of web formation) fiber alignment. As a general guide for pleated filters made from polypropylene webs, preferably about 55 to about 90% of the fibers are aligned at 90°±20° with respect to the row direction, and more preferably about 70 to about 85%. For webs made from other polymeric materials the numbers may be lower or higher. For example, as a general guide for pleated filters made from polyethylene terephthalate webs, preferably about 51 to about 80% of the fibers are aligned at 90°±20° with respect to the row direction, and more preferably about 60 to about 80%. As a general guide for pleated filters made from nylon webs, preferably about 51 to about 70% of the fibers are aligned at 90°±20° with respect to the row direction. Very highly aligned webs can be formed, e.g., webs having at least 80% of the collected fibers aligned at 90°±20° with respect to the row direction.

The disclosed webs have one or more anisotropic mechanical properties. One class of preferred webs may have at least a 2:1 ratio of the in-plane tensile strength in the direction transverse to the row direction to the tensile strength in the row direction using a 50 mm gauge length, and more preferably at least a 3:1 ratio. Another class of preferred webs may have at least a 2:1 ratio of the in-plane Taber Stiffness in the direction transverse to the row direction to the Taber Stiffness in the row direction, and more preferably at least about 2.2:1.

It is possible to construct the disclosed meltblowing apparatus and operate it under conditions that do not provide the disclosed aligned fiber webs, or under conditions that will provide weak webs poorly suited to filtration. For example, if insufficient secondary quench air is employed then the above-described oscillations may not occur and the fibers may not align substantially in the machine direction. Excessively high quench velocities may provide loftier webs having less interfiber bonding and entanglement and improved filtration performance, but having severely diminished mechanical properties such as stiffness and pleatability. Thus it generally will be preferable to employ secondary quench air within a range of mass flow ratios or volumes. As an example for webs made using polypropylene and secondary air chilled to below ambient temperature, a ratio of about 500 to about 2000 grams of secondary quench air per gram of extruded polymer may be preferred, as may be secondary quench air outlet velocities of about 15 to about 60 m/sec. These ranges may need to be adjusted empirically based on factors such as the meltblowing die and polymer employed, the target basis weight, target web solidity and target extent of fiber alignment and mechanical property anisotropy. Pulsation of the secondary quench air may also be employed but appears not to be necessary. Instead it appears to be better simply to adjust the secondary quench air flow upwards or downwards to a steady state value that provides collected webs having the desired final properties.

FIG. 2 shows a schematic overhead view of collector 26. Die 12 is positioned close to the leading edge of collector 26, but can be moved downweb to positions such as position 36 in order to alter the properties of web 28. Such repositioning may for example provide webs having reduced Taber Stiffness. If a conventional cylindrical collector surface is employed instead of a flat collector then it usually will be more difficult to obtain webs whose fibers are substantially aligned in the machine direction, and the webs may have lower Taber Stiffness. Excessive DCD lengths or excessive distances from the secondary quench air outlets to the collector may also be detrimental, e.g., by causing too many oscillations en route to the collector, excessive fiber attenuation or excessive fiber breakage.

Further details regarding the manner in which meltblowing would be carried out using an apparatus like that shown in FIG. 1 and FIG. 2 will be familiar to those skilled in the art.

The nonwoven filtration media can be further stiffened if desired using a variety of techniques. For example, an adhesive can be employed to laminate together layers of the filter media, e.g., as described in U.S. Pat. No. 5,240,479 (Bachinski). The filter media can also be made using conjugate fibers, e.g., as described in U.S. Pat. No. 5,709,735 (Midkiff et al.). Further details regarding the nonwoven filtration media can also be found in copending U.S. patent application Ser. No. ______(attorney docket no. 58214US002), filed even date herewith and entitled ALIGNED FIBER WEB, the disclosure of which is incorporated herein by reference.

FIG. 7 shows pleated filter media 100 having rows of pleats 102. The rows are aligned in the transverse direction, and the substantially-aligned fibers in web 100 are aligned at 90°±20° with respect to the row direction, that is, at ±20° with respect to the machine direction. FIG. 8 shows pleated filter media 100 and an expanded metal support 110 mounted in frame 112 to provide filter 114. The increased stiffness of pleated media 100 and the substantial machine direction fiber alignment transverse to the row direction both are believed to contribute to increased resistance of pleated media 100 to pleat deformation at high filter face velocities.

FIG. 10 shows an apparatus 120 for making the disclosed pleated filters. Aligned filtration media 122 is typically provided on a continuous roll 124. Media 122 may be slit to a desired width at slitting station 126. Media 122 may optionally be preheated at a heating station 128 to perform annealing or to make web 122 more flexible while passing into or through apparatus 120. In the illustrated embodiment, the heating station 128 is an infrared heater.

In one pleated filter embodiment, a reinforcing member 130 is applied to a rear face 132 of media 122 at location 134. Reference to the rear face 132 (or to the front face 164, discussed below) is for purposes of description only and does not indicate a required airflow orientation of the completed pleated filter. For example, the reinforcing member 130 may be positioned upstream or downstream in the air flow. Reinforcing member 130 may be applied in a variety of positions, e.g., as one or more continuous strips oriented in the machine direction 136, as discrete reinforcing members oriented transverse to the machine direction 136, or in other configurations that will be familiar to those skilled in the art. Reinforcing member 130 may be bonded to media 122 using a variety of techniques, such as adhesive bonding, thermal bonding, solvent bonding, or ultrasonic bonding. In this embodiment, location 134 is upstream from rotary-score pleater 138 which scores media 122 and reinforcing member 130 prior to pleating at pleat folding station 140. Infrared heaters 142 may optionally be provided for heat-setting the pleats 144. The pleats 144 are retained in an accumulator 146 and then advanced to a pleat spacing device 148 that retains the pleats 144 in the desired pleat spacing. Pleat formation and pleat spacing may be performed by a variety of methods, such as disclosed in U.S. Pat. No. 4,798,575 (Siversson '575), U.S. Pat. No. 4,976,677 (Siversson '677) and U.S. Pat. No. 5,389,175 (Wenz).

The resulting pleated filter media 100 is expanded to the desired pleat spacing in the pleat spacing device 148. One or more elongated, planar reinforcing strips 162 may optionally be applied to the pleat tips along the filter front face 164 at station 168 to maintain the pleat spacing. The reinforcing strips 162 may be bonded to the pleat tips by various techniques, such as adhesive bonding, thermal bonding, solvent bonding, or ultrasonic bonding, and can provide additional dimensional stability to the pleats 144. The pleated filter media 100 and optional reinforcing strip 162 can be cut to a desired size and shape. Pleated filter media 100 may be used in filtration applications, with or without a frame structure, or as an insert into a permanent or a reusable frame.

In another embodiment, a scrim 162 extending substantially across the entire front face 164 may be employed. Scrim 162 may be bonded to the pleat tips to provide additional dimensional stability to pleated filter media 100.

In yet another embodiment, one or more elongated, planar reinforcing strips 166 may optionally be bonded to the rear face 132 of pleated filter media 100 at station 168. In a further embodiment, the reinforcing strips 166 may be located over the reinforcing member 130 and opposite the reinforcing strips 162 to form truss structures as shown in FIG. 6 of Sundet et al. '011.

In embodiments where the pleated filter media 100 is formed without a surrounding frame, the pleated filter 172 exits the system 120 after the cutting station 186.

In a framed filter embodiment, a continuous strip of frame material 180 may be applied to the side edges of pleated filter media 100 parallel to the machine direction 136. An adhesive, such as a hot melt adhesive, may be applied to a first flange of a U-shaped channel formed from frame material 180 at station 187. An adhesive for sealing the ends of the pleats 144 may be applied at station 188. An adhesive may be applied to a second flange of the U-shaped channel at station 190. The frame material 180 may be bent into a U-shaped configuration at station 194. The ends of U-shaped channel may extend partially onto the front face 164 and rear face 132 of the pleated filter media 100. An assembly including the endless web of pleated filter media 100 and attached frame material 180 may be cut at station 186 to desired lengths. The pleated filter media 100 and reinforcing strips 162 may also be cut to size before application of frame material 180.

The pleated filter media 100 and side frames members 192 may be rotated 90° at location 191 to permit application of end frame members 196 at station 198 and formation of framed pleated filter 174. Framed pleated filter 174 may also be formed by configuring members 192, 196 as two box structures that are positioned over the first and second faces 132, 164, respectively, of pleated filter media 100, with overlapped circumferential portions, such as disclosed in U.S. Pat. No. 5,782,944 (Justice). In another embodiment, the frame member members 192, 196 can be configured as a one-sided die-cut frame that is folded around framed pleated filter 174.

The pleated filters 172, 174 are typically enclosed in suitable packaging. For typical HVAC applications, the pleat spacing is typically about 3 to about 6 pleats per 25.4 centimeters (1 inch). The pleat depth and filter thickness is typically about 25 centimeters to about 102 centimeters (1 inch to 4 inches). The filter length and width is typically about 30.5 centimeters×30.5 centimeters (12 inches×12 inches) to about 50.8 centimeters×122 centimeters (20 inches×48 inches).

Further details regarding pleated filter manufacture can be found in the above-mentioned Sundet et al. '011 and Sundet et al. '100 patents or will be familiar to those skilled in the art.

The disclosed pleated filters may be employed in a variety of applications including ventilation (e.g., furnace and clean room filters), pollution control (e.g., baghouse filters), liquid treatment (e.g., water filters), personal protection (e.g., protective suits with powered air supplies) and other applications that will be familiar to those skilled in the art.

The invention will now be described with reference to the following non-limiting examples, in which all parts and percentages are by weight unless otherwise indicated. Several measurements were carried out as follows:

Effective Fiber Diameter

Effective geometric fiber diameters were evaluated according to the method set forth in Davies, C. N., “The Separation of Airborne Dust and Particles,” Institution of Mechanical Engineers, London, Proceedings 1B, 1952.

Optical/Visual Web Properties

The overall visual web appearance was evaluated using a Zeiss Instruments dissecting microscope equipped with a charge coupled device camera having an 8 mm×14 mm magnification window.

Taber Stiffness

Web stiffness was evaluated using a Model 150-B TABER™ stiffness tester (commercially available from Taber Industries). Square 3.8 cm×3.8 cm sections were carefully vivisected from the webs using a sharp razor blade to prevent fiber fusion, and evaluated to determine their stiffness in the machine and transverse directions using 3 to 4 samples and a 15° sample deflection.

Stress-Strain

Stress-strain (or load vs. elongation) was measured using a Model 5544 INSTRON™ universal testing machine (commercially available from Instron Corp.). Rectangular 2.5 cm×6.3 cm sections were cut from the webs using a sharp razor blade and evaluated to determine the maximum force and elongation at maximum force, using 6 to 10 samples, a 50 mm initial jaw separation and a 3 cm/min stretch rate.

Filtration Quality Factor

Filtration quality factors (Q_(F)) were determined using a TSI™ Model 8130 high-speed automated filter tester (commercially available from TSI Inc.) and a dioctyl phthalate (“DOP”) challenge aerosol flowing at 42.5 L/min. Calibrated photometers were employed at the filter inlet and outlet to measure the DOP concentration and the % DOP penetration through the filter. An MKS pressure transducer (commercially available from MKS instruments) was employed to measure pressure drop (ΔP, mm H₂O) through the filter. The equation: $Q_{F} = \frac{- {\ln\left( \frac{\%\quad{DOP}\quad{penetration}}{100} \right)}}{\Delta\quad P}$ was used to calculate Q_(F). Q_(F) values can be reported as a curve plotting Q_(F) vs. the DOP challenge total mass after various time periods. However, the initial Q_(F) value usually provides a reliable indicator of overall performance, with higher initial Q_(F) values indicating better filtration performance and lower initial Q_(F) values indicating reduced filtration performance. Initial filtration quality factors Q_(F) of at least about 0.6 (using 100 ppm dioctyl phthalate particles having a size range between 10 and 700 nm traveling at a 7 cm/sec face velocity), more preferably at least about 0.8 and most preferably at least about 1 are preferred. Filtration Performance

Filtration performance was evaluated according to ASHRAE standard 52.2, “Method of Testing General Ventilation Air-Cleaning Devices for Removal Efficiency by Particle Size”. The ASHRAE standard evaluates filtration of a test aerosol containing laboratory-generated potassium chloride particles dispersed into an airstream. A particle counter measures and counts the particles in 12 size ranges upstream and downstream from the filter. The results can be reported as minimum composite efficiency values for particles in various size ranges. The minimum composite efficiency values correspond to the minimum percent particle retention (the downstream particle count/upstream particle count×100 for the size range in question) as the filter is loaded to a final pressure drop of 25.4 mm H₂O. A set of particle size removal efficiency performance curves at incremental dust loading levels may also be developed, and together with an initial clean performance curve may be used to form a composite curve representing the minimum performance in each size range. Points on the composite curve are averaged and the averages used to determine the minimum efficiency reporting value for the filter.

EXAMPLES 1-3 AND COMPARISON EXAMPLE 1 Polypropylene Webs

A conventional 20.5 cm wide meltblowing apparatus was modified by addition of a secondary air quench system and a flat-bed collector arranged as in FIG. 1. In a conventional blown microfiber process, secondary quench air would not be employed and the web would be collected on a rounded surface such as a porous drum. The modified apparatus was used to make meltblown polypropylene webs whose fibers were highly aligned in the machine direction. The secondary air quench system employed two opposed horizontally-disposed 76 cm wide×51 cm high air outlets disposed approximately 6 cm below the meltblowing die tip, dispensing 12-13° C. chilled air flowing at various rates (or not at all) through the air outlets. The flat-bed collector employed a vacuum collection system located under the bed. The meltblowing die was positioned over the leading edge of the collector. FINA™ type 3960 polypropylene (commercially available from Fina Oil and Chemical Co.) was melted in an extruder operated at 265° C. and fed at 9.1 kg/hr to the meltblowing die. The die was maintained at about 265° C. using resistance heaters and supplied with 300° C. primary air flowing at 4.2 m³/min. The DCD was adjusted to provide webs having a 0.5 mm H₂O pressure drop at a 32.5 L/min flow rate. For webs prepared using secondary quench air, the DCD was approximately 20 cm. For webs prepared without secondary quench air, the DCD was approximately 34 cm. The collector vacuum was adjusted to provide webs having 8-9% solidity. The collector vacuum was 3250 N/m² for webs prepared using secondary quench air at 50 or 35 m/sec outlet velocity, 5000 N/m² for webs prepared using secondary quench air at 17 m/sec outlet velocity, and zero for webs prepared without secondary quench air. The collected webs had an 80 g/m² basis weight and a 19 μm EFD. The webs were corona-treated as described in U.S. Pat. No. 4,588,537 to Klasse et al., hydrocharged as described in U.S. Pat. No. 5,908,598 to Rousseau et al. and evaluated to determine their mechanical properties and filtration quality factor Q_(F). The webs were also heat treated at 126° C. for 5 minutes and reevaluated to determine their mechanical properties.

Set out below in Table 1 are the Example No. or Comparison Example No., secondary air velocity and mass flow ratio, the fiber count and fiber alignment data, and the filtration quality factor Q_(F) for each web. Set out below in Table 2 are the machine direction (“MD”) and transverse direction (“TD”) Taber Stiffness and tensile strength values for the each web, and the ratio of MD to TD Taber Stiffness and tensile strength. Set out below in Table 3 are the MD and TD Taber Stiffness and tensile strength values for the heat treated webs, and the ratio of MD to TD Taber Stiffness and tensile strength. TABLE 1 Example Secondary No. of Fibers No. of Fibers No. or Air Mass Total No. Fibers within Fibers within Filtration Comp. Velocity at Ratio, of within 0-10° of within 0-20° of Quality Example Outlet Secondary Measured 0-10° of MD 0-20° of MD Factor, No. (m/sec) Air:Polymer Fibers MD (%) MD (%) QF 1 50 1770 38 30 80 34 89 1.65 2 35 1450 33 20 61 27 82 1.5 3 17 720 32 16 50 32 56 0.85 Comp. 0 0 33 11 33 33 57 0.7 Ex.1

TABLE 2 Secondary Ratio, Tensile Tensile Ratio, Example No. Air Velocity Mass Ratio, Taber Taber Taber Strength, Strength, Tensile or Comp. at Outlet Secondary Stiffness, Stiffness, Stiffness MD TD Strength Example No. (m/sec) Air:Polymer MD TD MD:TD (dynes) (dynes) MD:TD 1 50 1770 1.3 0.6 2.2 1773 635 2.8 2 35 1450 1.9 0.7 2.7 2270 730 3.1 3 17 720 2.1 1.1 1.9 1374 1101 1.2 Comp. Ex. 1 0 0 1.5 1.3 1.2 1670 1370 1.2

TABLE 3 (Heat Treated) Secondary Ratio, Tensile Tensile Ratio, Example No. Air Velocity Mass Ratio, Taber Taber Taber Strength, Strength, Tensile or Comp. at Outlet Secondary Stiffness, Stiffness, Stiffness MD TD Strength Example No. (m/sec) Air:Polymer MD TD MD:TD (dynes) (dynes) MD:TD 1 50 1770 1.2 0.7 1.7 2298 780 2.9 2 35 1450 1.9 0.7 2.7 2303 765 3.0 3 17 720 2.5 1.6 1.6 1770 1100 1.6 Comp. Ex. 1 0 0 2.5 2.0 1.3 1700 1489 1.1

As shown in Table 1, webs made using secondary quench air had significantly greater machine direction fiber alignment than webs made without secondary quench air. This is further illustrated in FIGS. 3-6, which are polar “radar” plots respectively showing the number and orientation (in degrees with respect to the 0° machine direction) of fibers in Examples 1-3 and Comparison Example 1. Because fibers oriented at 0° with respect to the machine direction could also be said to be oriented at 180°, the plots have symmetric lobes reflected about the origin. FIG. 3 shows for example that 12 fibers were oriented at 0° with respect to the machine direction, 9 fibers were oriented at −10°, 8 fibers were oriented at +10°, 6 fibers were oriented at −20°, and so on. FIGS. 3-5 show that the disclosed webs had considerably greater machine direction alignment than the web prepared without secondary quench air plotted in FIG. 6. In a further comparison, the FIG. 4 web shown in the Lau et al. '749 patent was evaluated to determine its fiber orientation and fiber count, and found to have only 50% of its fibers aligned within ±20° of the machine direction.

The FIG. 3-5 plots generally mirror the behavior of a wetting fluid placed on the non-collector side of the web. If a drop of a suitable wetting fluid (preferably colored to aid in observation) is so placed it will tend to spread into the web in an oblong pattern generally corresponding to the radar plot lobe shapes, thus providing a convenient indicator of the primary direction of fiber orientation and web formation. When a wetting fluid is placed on the Comparison Example 1 web, it tends to spread more or less evenly outward in an expanding circular pattern.

Table 1 also shows that as the secondary quench air volume increased, the filtration quality factor Q_(F) increased and then decreased slightly.

Webs prepared using secondary air had visible striations generally aligned in the machine direction, a surface with an overall smooth sheen and slight fuzziness, and few or none of the nodules that usually are found in conventional blown microfiber webs. Fibers having approximately 2 to 5 cm lengths could be teased from the webs using tweezers. Webs prepared without secondary quench air visually resembled standard blown microfiber webs collected on a round collector. Some relatively short (less than 1 cm) individual fibers could be removed from these webs using tweezers, but only with great difficulty.

As shown in Table 2, webs made using secondary quench air had significantly more anisotropic Taber Stiffness than webs made without secondary quench air. Webs made using higher volumes of secondary quench air also had significantly more anisotropic tensile strength than webs made without secondary quench air.

As shown in Table 3, heat treating could be used to increase web stiffness and tensile strength. For several of the webs this could be done without causing a substantial change in the web's overall mechanical anisotropy as measured using MD:TD property ratios.

EXAMPLES 4-6 Smaller EFD Webs

Using the general method of Example 1, meltblown polypropylene webs were prepared using 300° C. primary air flowing at 3.4 m³/min and secondary quench air and collector vacuum adjusted to provide collected webs having an 80 g/m² basis weight, 8-9% solidity and smaller effective fiber diameters than were obtained in Example 1. Set out below in Table 4 are the Example No., secondary air velocity and mass flow ratio, effective fiber diameter and the fiber count and fiber alignment data for the resulting webs. TABLE 4 Secondary Fibers Fibers Air Velocity Mass Ratio, Total No. of No. of Fibers within 0-10° No. of Fibers within 0-20° Example at Outlet Secondary Measured within 0-10° of MD within 0-20° of MD No. (m/sec) Air:Polymer EFD Fibers of MD (%) of MD (%) 4 22.5 930 13.5 38 24 63 29 76 5 20 830 13.4 41 20 49 26 63 6 14.5 620 7.4 43 18 42 26 60

As shown in Table 4, webs having substantial machine direction fiber alignment could be made at a variety of effective fiber diameters.

EXAMPLES 7-10 AND COMPARISON EXAMPLES 2 and 3 PET and Nylon Webs

Using the general method of Example 1, polyethylene terephthalate (“PET”) and nylon (ULTRAMID™ BS-400N nylon, commercially available from BASF Corp.), were employed to prepare nonwoven webs using 350° C. primary air flowing at 2.9 m³/min and optional secondary quench air. A 12.7 cm DCD was used to prepare the PET webs and a 16.5 cm DCD was used to prepare the nylon webs. The collected PET webs had an 85 g/m² basis weight, 5-6% solidity and a 16 μm EFD. The collected nylon webs had a 70 g/m² basis weight, 5-6% solidity and a 17-18 μm EFD. Set out below in Table 5 are the Example No. or Comparison Example No., secondary air velocity and mass flow ratio, polymer employed and the fiber count and fiber alignment data for the resulting webs. TABLE 5 Secondary Example Air Total No. No. of Fibers No. of Fibers No. or Velocity Mass Ratio, of Fibers within 0-10° Fibers within 0-20° Comp. at Outlet Secondary Measured within 0-10° of MD within 0-20° of MD Ex. No. (m/sec) Air:Polymer Polymer Fibers of MD (%) of MD (%)  7 35 1450 PET 41 26 63 32 78  8 22.5 930 PET 36 21 58 25 69 Comp. 0 0 PET 38 9 23 12 31 Ex. 2  9 35 1450 Nylon 33 17 50 21 64 10 22.5 930 Nylon 45 16 35 23 52 Comp. 0 0 Nylon 38 10 26 19 50 Ex. 3

As shown in Table 5, webs having substantial machine direction fiber alignment could be made using a variety of polymers.

EXAMPLE 11 Additive

Example 2 was repeated using a 1.5% addition of the additive poly(4-methyl-1-pentene). This increased the filtration quality factor Q_(F) from 1.5 without the additive to 1.7 with the additive.

EXAMPLE 12 Additives

Example 11 was repeated using a 1.5% addition of the additive poly(4-methyl-1-pentene) and a 0.5% addition of CHIMASSORB 944 hindered amine light stabilizer. The web was hydrocharged but not corona-treated. The filtration quality factor Q_(F) was 2.5, and more than double that obtained using webs made from conventional untreated polypropylene blown microfibers made without secondary quench air.

EXAMPLE 13 AND COMPARISON EXAMPLE 4 Q_(F) Evaluation Over Time

Using the general method of Example 1, meltblown polypropylene webs were prepared with and without secondary quench air flowing at a 1770 secondary quench air:polymer mass flow ratio, corona-treated, hydrocharged, and evaluated to determine their filtration quality factor Q_(F). The webs had an 85 g/m² basis weight, 19-21 μm EFD, and a pressure drop of 0.4-0.5 mm H₂O at 42.5 L/min. Set out below in Table 6 are the Q_(F) factors after various cumulative DOP exposure levels for the web made with (Example 13) or without (Comparison Example 4) secondary quench air. TABLE 6 Cumulative DOP Comparison Challenge, Example 13 Example 4 (mg) Web, Q_(F) Web, Q_(F) Initial 1.8 0.7  50 1 0.2 100 0.6 0.15 150 0.45 0.1 200 0.3 <0.1

As shown in Table 6, a web made using secondary quench air and having substantial machine direction fiber alignment provided significantly better filtration performance than a web made without secondary quench air and having less fiber alignment.

EXAMPLES 14 AND 15 AND COMPARISON EXAMPLES 5-7 Pleated Furnace Filters

The corona-treated and hydrocharged Example 2 webs, the corona-treated and hydrocharged Comparison Example 1 webs and a sample of ACCUAIR# corona-treated spunbond polyethylene/polypropylene twinned fiber web (71 g/m² basis weight, ˜20 μm EFD, commercially available from Kimberly Clark Corp.) were formed into 50.8 cm×63.5 cm×2.1 cm high filter elements having pleats 102 like pleated media 100 shown in FIG. 7. The pleats 102 were arranged so that the folds were aligned with the transverse direction, with 87 pleats (13.8 pleats/10 cm) along the long dimension. The pleated media 100 was sandwiched between and glued to expanded metal supports like support 110 and mounted in a cardboard frame like frame 112 shown in FIG. 8 to form a framed filter like filter 114. The finished filters were evaluated for filtration performance according to ASHRAE standard 52.2, “Method of Testing General Ventilation Air-Cleaning Devices for Removal Efficiency by Particle Size” at a 1.5 m/sec face velocity. The results reported below in Table 7 show the minimum composite efficiency values for particles in the size ranges 0.3 to 1 μm, 1 to 3 μm and 3 to 10 μm. Table 7 also reports the total filter weight gain (total particulate weight captured by the filter) after completion of the evaluation. Higher minimum composite efficiency and total filter weight gain values correspond to better filtration, longer service life or both better filtration and longer service life. TABLE 7 Total Minimum Filter Composite Weight Example Initial Efficiency (%) Gain, No. or Pressure 0.1 1 3 25.4 mm Comp. Web Web Drop, mm to to to H₂O Ex. No. Employed Treatment H₂O 1 μm 3 μm 10 μm (g) 14 Example 2 Corona- 4.9 43 81 91 35 treated 15 Example 2 Corona- 5.1 53 89 97 37.1 treated and hydrocharged Comp. Comp. Ex. 1 Corona- 4.6 36 71 86 23.8 Ex. 5 treated Comp. Comp. Ex. 1 Corona- 4.6 42 81 93 33.9 Ex. 6 treated and hydrocharged Comp. ACCUAIR Corona- 4.6 41 80 91 26.1 Ex. 7 web treated

As shown in Table 7, corona-treated or corona-treated and hydrocharged meltblown nonwoven webs made using secondary quench air and having substantial machine direction fiber alignment (Examples 14 and 15) provided much better minimum composite efficiency at a 1 mm H₂O pressure drop than otherwise similar meltblown nonwoven webs made without secondary quench air and having less fiber alignment (Comparison Examples 5 and 6). The Example 14 and Example 15 webs also had comparable or better minimum composite efficiency than a commercial spunbond nonwoven web (Comparison Example 7). The Example 14 and Example 15 webs had better particle capture (as evidenced by their higher total filter weight gain values) than the Comparison Example 5-7 webs.

EXAMPLES 16-18 AND COMPARISON EXAMPLE 8 Pleated Furnace Filter Pressure Drop vs. Face Velocity Evaluation

Using the general method of Examples 14 and 15, a meltblown aligned fiber polypropylene web was corona-treated and hydrocharged but not heat treated. This web had a 1.7 MD Taber Stiffness value and is identified below as the web of Example 16. A stiffer web was prepared using corona-treatment, hydrocharging and heat treatment. This web had a 2.2 MD Taber Stiffness value and is identified below as the web of Example 17. A yet stiffer web was prepared using a 1.5% addition of the additive poly(4-methyl-1-pentene), corona-treatment, hydrocharging and heat treatment. This web had a 3.7 MD Taber Stiffness value and is identified below as the web of Example 18. The Example 16-18 webs and a sample of ACCUAIR corona-treated spunbond polyethylene/polypropylene twinned fiber web (having a 2.1 MD Taber Stiffness and identified below as the web of Comparison Example 8) were formed into 30 cm×27 cm×2.1 cm high filter elements having pleats 102 like filter media 100 shown in FIG. 7. The filters had 13.8 pleats/10 cm along the long dimension, and were sandwiched between and glued to expanded metal supports like support 110 in FIG. 8. In a series of runs, each such filter was mounted in a PLEXIGLAS™ plastic frame whose transparent side plates permitted the pleat edges to be photographed. The frame side plates touched the filtration media edges but permitted pleat movement. The frame was mounted atop a vacuum table and exposed to air from a downwardly-directed box fan. The filters were loaded by sprinkling a synthetic dust made from a 50:50 mixture of SAE Fine Test Dust and talc into the air stream until the filter pressure drop reached about 0.35 in (0.9 cm) of water at an approximate 1.5 m/sec face velocity. This simulated a substantial natural loading level. Set out below in Table 8 are the filter descriptions, MD Taber Stiffness values and total filter weight gain values. TABLE 8 Example No. or MD Taber Total Filter Weight Gain Comp. Ex. No. Stiffness (g) 16 1.7 37.9 17 2.2 40.2 18 3.7 33.4 Comp. Ex. 8 2.1 36.2

The filters were next mounted in a duct equipped with an anemometer and exposed to flowing air at velocities sufficient to cause pressure drops between about 0.2 in. (0.5 cm) of water and 1.2 in. (3 cm) of water. The Example 16 (1.7 MD Taber Stiffness) filter began to exhibit noticeable pleat deformation, manifested by pinching together of the pleats at the filter air inlet side, at a 0.35 in (0.9 cm) pressure drop. The Example 17 (2.2 MD Taber Stiffness) and Comparison Example 8 filters began to exhibit noticeable pleat deformation at a 0.5 in (1.3 cm) pressure drop. The Example 18 (3.7 MD Taber Stiffness) filter did not exhibit noticeable pleat deformation even at a 1.2 in (3 cm) pressure drop. FIG. 9 shows a plot of the pressure drop (in inches of water) vs. anemometer reading (in nominal units) for the filters of Example 16 (curve 116), Example 17 (curve 117), Example 18 (curve 118) and Comparison Example 8 (curve 119). As shown in FIG. 9, the Example 18 filter exhibited a linear increase in pressure drop as airflow increased, whereas the other tested filters exhibited a non-linear response, indicative of pleat distortion, as airflow increased.

Various modifications and alterations of this invention will be apparent to those skilled in the art without departing from this invention. This invention should not be restricted to that which has been set forth herein only for illustrative purposes. 

1. A filter element that comprises: a nonwoven filtration web that has rows of folded pleats and that contains thermoplastic fibers, a majority of which fibers are aligned at 90°±20° with respect to the row direction.
 2. A filter element according to claim 1 wherein about 55 to about 90% of the fibers are aligned at 90°±20° with respect to the row direction.
 3. A filter element according to claim 1 wherein about 70 to about 85% of the collected fibers are aligned at 90°±20° with respect to the row direction.
 4. A filter element according to claim 1 wherein fibers having lengths of about 2-5 cm can be teased from the web.
 5. A filter element according to claim 1 wherein the fibers have an average effective fiber diameter of about 8 to about 25 μm.
 6. A filter element according to claim 1 wherein the web has at least a 2:1 ratio of the in-plane tensile strength in the direction transverse to the row direction to the tensile strength in the row direction using a 50 mm gauge length.
 7. A filter element according to claim 1 wherein the web has at least a 4:1 ratio of the in-plane tensile strength in the direction transverse to the row direction to the tensile strength in the row direction using a 50 mm gauge length.
 8. A filter element according to claim 1 wherein the web has at least a 2:1 ratio of the in-plane Taber Stiffness in the direction transverse to the row direction to the Taber Stiffness in the row direction.
 9. A filter element according to claim 1 wherein the web has at least a 2.2:1 ratio of the in-plane Taber Stiffness in the direction transverse to the row direction to the Taber Stiffness in the row direction.
 10. A filter element according to claim 1 wherein the major surfaces of the web exhibit striations corresponding to substantial alignment of individual fibers transverse to the row direction.
 11. A filter element according to claim 1 wherein a wetting fluid placed on the web preferentially wicks transverse to the row direction.
 12. A filter element according to claim 1 wherein the web has been annealed.
 13. A filter element according to claim 1 wherein the web has been corona-treated or hydrocharged.
 14. A method of making a pleated filter element, which method comprises: forming rows of pleats in a nonwoven filtration web that comprises thermoplastic fibers, a majority of which fibers are aligned at 90°±20° with respect to the row direction; and cutting the pleated filter element to a desired size and shape.
 15. A method according to claim 14 wherein about 55 to about 90% of the fibers are aligned at 90°±20° with respect to the row direction.
 16. A method according to claim 14 wherein about 70 to about 85% of the collected fibers are aligned at 90°±20° with respect to the row direction.
 17. A method according to claim 14 wherein fibers having lengths of about 2-5 cm can be teased from the web.
 18. A method according to claim 14 wherein the fibers have an average effective fiber diameter of about 8 to about 25 μm.
 19. A method according to claim 14 wherein the web has at least a 2:1 ratio of the in-plane tensile strength in the direction transverse to the row direction to the tensile strength in the row direction using a 50 mm gauge length.
 20. A method according to claim 19 wherein the web has a filtration quality factor Q_(F) of at least about 0.6 using 100 ppm dioctyl phthalate particles having a size range between 10 and 700 nm traveling at a 7 cm/sec face velocity.
 21. A method according to claim 14 wherein the web has at least a 4:1 ratio of the in-plane tensile strength in the direction transverse to the row direction to the tensile strength in the row direction using a 50 mm gauge length.
 22. A method according to claim 14 wherein the web has at least a 2:1 ratio of the in-plane Taber Stiffness in the direction transverse to the row direction to the Taber Stiffness in the row direction.
 23. A method according to claim 14 wherein the web has at least a 2.2:1 ratio of the in-plane Taber Stiffness in the direction transverse to the row direction to the Taber Stiffness in the row direction.
 24. A method according to claim 14 wherein the major surfaces of the web exhibit striations corresponding to substantial alignment of individual fibers transverse to the row direction.
 25. A method according to claim 14 wherein a wetting fluid placed on the web preferentially wicks transverse to the row direction.
 26. A method according to claim 14 wherein the web has been annealed.
 27. A method according to claim 14 wherein the web has been corona-treated or hydrocharged.
 28. A method according to claim 20 wherein the web has a filtration quality factor Q_(F) of at least about 0.6 using 100 ppm dioctyl phthalate particles having a size range between 10 and 700 nm traveling at a 7 cm/sec face velocity. 